Do You Know what Molten Color is?

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FAQ:"A client is asking me to measure something they call "Molten Color'. Do you have any information on this? Do Hunterlab instrument have a function for this color?"

"Molten Color" is not a defined color scale but refers to melting chemical crystalline or powder material such as Maleic or Phthalic Anhydride, into a liquid at an elevated temperature in the 140 – 250 C range.

Industrial Standard References for Molten Color Applications

APHA/Pt-Co Color measurement is a color quality attribute of BPA Bisphenol A, Cresylic Acids, Maleic and Phthalic Anhydride; Cresylic Acids and solid aromatic hydrocarbons prepared by heating to a liquid form.

  • ASTM D1686 Test Method for Color of Solid Aromatic Hydrocarbons and Related Materials in the Molten State (Platinum-Cobalt Scale)
  • ASTM D3366 Standard Test Method for Color of Maleic Anhydride and Phthalic Anhydride in the Molten State and After Heating (Platinum-Cobalt Scale)
  • ASTM D3627 Standard Test Method for Color of Cresylic Acids ("C" Series Standards)
  • ASTM D4789 Standard Test Method for Solution Color of Bisphenol A (4,4´-Isopropylidenediphenol)

ASTM - American Society of Testing and Materials, West Conshohocken, PA USA www.astm.org

After preparation of the hot liquid sample as shown in HunterLab application note, AN 1030 Hot Liquids, liquid is measured in total transmission using CIE L*, a*, b* D65/10 color values as a full color descriptor, or typically using a specialized yellowness scale such as APHA/Pt-Co/Hazen Color, Yellowness Index per ASTM E313, or Gardner Color.

The higher the yellowness; the greater the presence of impurities. Typical APHA/Pt-Co/Hazen color values are between 0 – 100 for these products.

FAQ: "Color instruments measure color in reflectance or transmission. Why not just measure the color of the Maleic or Phthalic Anhydride in the crystalline or powder form?”

Impurities related to processing, storage or shipping found in these products result in absorbance in the blue region of the visible spectrum and visually show as trace amounts of yellowness. These small amounts of yellowness are visually lost in the light scattering from the crystalline or powder.

Impurities related to processing, storage or shipping result in absorbance in the blue region of the visible spectrum and visually show as trace amounts of yellowness. These small amounts of yellowness are visually lost in the light scattering from the crystalline or powder forms.

By melting the crystals or powder all this “optical noise” is removed. Standardization on cell or vial in transmission negates the effects of the cell and solvent leaving just the color of the impurities to be measured by a specialized yellowness metric.

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